I heard this on True Blood tonight and almost died from excitement. One of my favorite Neko Case songs. I saw her live when she was here in Savannah a few years ago and had chill bumps the entire time she was singing this.
There are very few contemporary artists that can reach into your chest and grab your soul with just their voice. I would say that Adele, Florence Welch, and Neko Case are three of the best.